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Scientific Paper

Kinetics of viscoelasticity in the electric double layer following steps in the electrode potential studied by a fast electrochemical quartz crystal microbalance (EQCM)

Journal article 2021

Christian Leppin, Astrid Peschel, Frederick Sebastian Meyer, Arne Langhoff, Diethelm Johannsmann

Analyst, 146 (7), 2160–2171, 2021

View at publisher ↗

DOI 10.1039/d0an01965h

Summary

A fast electrochemical QCM followed the electric double layer after steps in electrode potential. The overtones scale as in simple mass loading and the bandwidth changes little, but the size of the signal and its timing, matching the charging time from impedance spectroscopy, point to changes in the viscosity of the diffuse layer rather than adsorption.

Summary written by the openQCM team. The original abstract is on the publisher’s page.

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