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Scientific Paper

Steering diffusion selectivity of chemical isomers within aligned nanochannels of metal-organic framework thin film

Cover image for Steering diffusion selectivity of chemical isomers within aligned nanochannels of metal-organic framework thin film
Journal article 2024

Tanmoy Maity, Susmita Sarkar, Susmita Kundu, Suvendu Panda, Arighna Sarkar, Raheel Hammad, Kalyaneswar Mandal, Soumya Ghosh, Jagannath Mondal, Ritesh Haldar

Nature Communications, 15 (1), 1–9, 2024

View at publisher ↗ Full text ↗

DOI 10.1038/s41467-024-53207-3

Summary

Diffusion of chemical isomers through the oriented, ångström-scale channels of a metal-organic framework thin film is measured by kinetic mass uptake and modelled by simulation. The work reveals a dynamic chemical interaction between the guest molecules and the framework and uses it to reverse the diffusion selectivity between positional haloalkane isomers, a route to better membrane separations and selective catalysis.

Summary written by the openQCM team. The original abstract is on the publisher’s page.

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