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Scientific Paper

Rheology of the Electric Double Layer in Electrolyte Solutions

Journal article 2020

Riccardo Funari, Atsushi Matsumoto, John R. de Bruyn, Amy Q. Shen

Analytical Chemistry, 92 (12), 8244–8253, 2020

View at publisher ↗ Full text ↗

DOI 10.1021/acs.analchem.0c00475

Summary

Resonance frequency and dissipation of a QCM immersed in sodium chloride, an ionic liquid (BmimCl) and ethylene glycol solutions are used to estimate the shear modulus of the electric double layer. Its storage and loss moduli rise steeply below 1 M and then saturate, with a near-surface viscosity about 50 times (NaCl) and 500 times (BmimCl) that of the bulk.

Summary written by the openQCM team. The original abstract is on the publisher’s page.

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