Scientific Paper
Kinetics of Photochemical and Mechanochemical Organic Reactions on Surface
Summary
PhD thesis on reactions driven by light and by force at surfaces. It reviews scanning probe lithography for mechanochemistry, makes patterns of stimuli-responsive polymer brushes that hide information in the same area, and uses elastomeric tip arrays to apply controlled force and time to surface Diels–Alder reactions, measuring rate constants, activation energies and activation volumes for four systems.
Summary written by the openQCM team. The original abstract is on the publisher’s page.
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