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Scientific Paper

Highly permeable perfluorinated sulfonic acid ionomers for improved electrochemical devices: insights into structure–property relationships

Journal article 2020

Adlai Katzenberg, Anamika Chowdhury, Minfeng Fang, Adam Z Weber, Yoshiyuki Okamoto, Ahmet Kusoglu, Miguel A Modestino

Journal of the American Chemical Society, 142 (8), 3742–3752, 2020

View at publisher ↗

DOI 10.1021/jacs.9b09170

Summary

A new perfluorinated sulfonic acid ionomer whose glassy amorphous backbone (PFMMD) replaces the PTFE matrix of commercial materials. It limits swelling of the ionic domains and disrupts crystallinity, trading a slight loss of proton conductivity for much higher gas permeability, which could improve fuel-cell electrodes with low platinum loading when used as catalyst binder.

Summary written by the openQCM team. The original abstract is on the publisher’s page.

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